Those extensions are standardized ways to broadcast information that might be useful to your contacts (they will receive those information only if they have indicated their interest in them).
The events are also shown in the contact list, next to the contact line:
On the above figure, A stands for Activity, M for Mood, and G for Gaming.
The details are shown with notifications if configured, and in the detailed contact information window, on the bottom left in the contact list tab.
You can see below the list of the related options and commands.
All the display_foo_notifications options can be tab-specific, so you can display those notifications only for a specific contact, or the other way around.
There is no /tune command because it wouldn’t be really useful. There was originally a way to broadcast the current tune with the mpd plugin, but it was no good. You should use an external script to do that, or use a player that has the feature.